激光焦平面变化对LA-ICPMS锆石U-Pb定年准确度的影响   总被引：3，自引：0，他引：3  

于超  杨志明  周利敏  张亮亮  李振清  赵苗  张佳钰  陈微言  索明石 《矿床地质》2019,38(1):21-28

元素分馏是影响LA-ICPMS锆石U-Pb定年准确度的重要因素之一,通常利用标样进行校正。激光聚焦位置变化会引起剥蚀坑形貌及U-Pb分馏的改变,标样和样品聚焦条件不一致将导致标样难以准确校正样品,并最终影响定年结果的准确性,但影响的程度、机制及可容忍范围目前尚不清楚。为此,文章以91500为标样、GJ-1为样品,详细研究了聚焦偏离30μm范围内剥蚀标样与样品锆石的剥蚀坑形貌变化以及由此导致的U-Pb定年误差。实验表明,在距离锆石表面30μm范围内,标样和样品焦平面同步变化时,二者U-Pb分馏形式及程度基本一致,激光焦平面偏离所引起的样品年龄与TIMS推荐值的偏差小于1%;当二者聚焦不同步时,标样与样品的U-Pb分馏差别显著,年龄偏差最大可超过3%。激光聚焦不同步导致的标样与样品剥蚀坑纵横比差异是引起年龄误差的根本原因,激光焦平面偏离锆石表面超过15μm,剥蚀坑坑口明显变大,纵横比减小,U-Pb分馏形式及程度发生改变。通过预剥蚀锆石,观察剥蚀坑轮廓,使激光焦平面在距离锆石样品表面15μm范围内,可确保标样与样品剥蚀坑形貌及U-Pb分馏状态一致,提高LA-ICPMS定年的准确度。  相似文献   

Evidence for Amazonian acidic liquid water on Mars—A reinterpretation of MER mission results     

Alberto G. Fairén  Dirk Schulze-Makuch  Wolfgang Fink  Esther R. Uceda  Ricardo Amils 《Planetary and Space Science》2009,57(3):276-318

The Mars Exploration Rover (MER) missions have confirmed aqueous activity on Mars. Here we review the analyses of the field-based MER data, and conclude that some weathering processes in Meridiani Planum and Gusev crater are better explained by late diagenetic water-rock interactions than by early diagenesis only. At Meridiani, the discovery of jarosite by MER-1 Opportunity indicates acidic aqueous activity, evaporation, and desiccation of rock materials. MER-based information, placed into the context of published data, point to local and limited aqueous activity during geologically recent times in Meridiani. Pre-Amazonian environmental changes (including important variations in the near-surface groundwater reservoirs, impact cratering, and global dust storms and other pervasive wind-related erosion) are too extreme for pulverulent jarosite to survive over extended time periods, and therefore we argue instead that jarosite deposits must have formed in a climatically more stable period. Any deposits of pre-existent concretionary jarosite surviving up to the Amazonian would not have reached completion in the highly saline and acidic brines occurring at Meridiani. MER-2 Spirit has also revealed evidence for local and limited Amazonian aqueous environmental conditions in Gusev crater, including chemical weathering leading to goethite and hematite precipitation, rock layering, and chemical enhancement of Cl, S, Br, and oxidized iron in rocks and soils. The estimated relative age of the impact crater materials in Gusev indicates that these processes have taken place during the last 2 billion years. We conclude that minor amounts of shallow acidic liquid water have been present on the surface of Mars at local scales during the Amazonian Period.  相似文献   

内蒙古海拉尔发现陨石坑及科研意义     

肖荣阁  杨帆  李娜  屈云燕 《化工矿产地质》2012,34(2):95-102

陨石撞击构造研究是天文地质学研究的热点,但是缺乏典型的研究基地,海拉尔陨石坑的发现,无疑是一个重要补充。海拉尔陨石坑坑区基础岩石为晚侏罗世火山岩,区域自然地理为平缓丘陵山地草原,陨石坑呈封闭圆形,中间筒状突起显示冲击锥地貌,直径320m,坑底到坑缘最大高差10m。为了保护性研究,没有进行进行破坏性取样分析撞击岩石矿物,根据排他比较分析法,认为该坑唯有陨石撞击成因可以解释,并且具有最关键的冲击锥地貌特征。这是一个我国唯一保存完整的可供直观参观的陨石坑,估计该陨石坑年龄应该在100万年以上。  相似文献   

Bulk compositions of metallic Fe-Ni of chondrites： Constraints on fractionation of siderophile and chalcophile elements     

XU Lin    LIN Yangting  WANG Shijie    OUYANG Ziyuan Key Laboratory of the Study of Earth’s Deep Interior  Institute of Geology  Geophysics  Chinese Academy of Sciences  Beijing  China National Astronomical Observatories  Beijing  China Institute of Geochemistry  Guiyang  China 《中国地球化学学报》2009,28(3):271-278

Bulk compositions of metallic Fe-Ni from two equilibrated ordinary chondrites, Jilin (H5) and Anlong (H5), and two unequilibrated ones, GRV 9919 (L3) and GRV 021603 (H3), were analyzed by inductively coupled plasma mass spectrometry (ICP-MS). The CI-, Co-normalized abundances of siderophile and chalcophile elements of metallic Fe-Ni from the unequilibrated ordinary chondrites correlate with 50% condensation temperatures (i.e., volatility) of the elements. The refractory siderophile elements (i.e., platinum group elements, Re), Au, Ni and Co show a flat pattern (1.01×CI Co-normalized), while moderate elements (As, Cu, Ag, Ga, Ge, Zn) decrease with volatility from 0.63×CI (Co-normalized, As) to 0.05×CI (Co-normalized, Zn). Cr and Mn show deficit relative to the trend, probably due to their main partition in silicates and sulfides (nonmagnetic). Metallic Fe-Ni from the equilibrated ordinary chondrites shows similar patterns, except for strong deficit of Cr, Mn, Ag and Zn. It is indicated that these elements were almost all partitioned into silicates and/or sulfides during thermal metamorphism. The similar deficit of Cr, Mn, Ag and Zn was also found in iron meteorites. Our analyses demonstrate similar behaviors of W and Mo as refractory siderophile elements during condensation of the solar nebula, except for slight depletion of Mo in the L3 and H5 chondrites. The Mo-depletion of metallic Fe-Ni from GRV 9919 (L3) relative to GRV 021603 (H3) could be due to a more oxidizing condition of the former than the latter in the solar nebula. In contrast, the Mo-depletion of the metallic Fe-Ni from the H5 chondrites may reflect partition of Mo from metal to silicates and/or sulfides during thermal metamorphism in the asteroidal body.  相似文献   

SIMS Pb/Pb dating of Zr-rich minerals in lunar meteorites Miller Range 05035 and LaPaz Icefield 02224:Implications for the petrogenesis of mare basalt   总被引：1，自引：0，他引：1  

HSU WeiBiao 《中国科学:地球科学(英文版)》2010,(3)

Miller Range (MIL) 05035 and LaPaz Icefield (LAP) 02224 are unbrecciated lunar basalt meteorites. In this report, we studied their petrography and mineralogy and made in situ uranogenic Pb/Pb dating of Zr-rich minerals. Petrography and mineralogy of these two lunar meteorites are consistent with previous investigations. The zirconolite Pb/Pb age of MIL 05035 is 3851±8 Ma (2σ), in excellent agreement with previous reports. This age suggests that MIL 05035 could be paired with Asuka 881757, a low-Ti mare basalt meteorite. The magmatic event related to MIL 05035 was probably due to the late heavy impact bom- bardment on the moon around 3.9 Ga. One baddeleyite grain in LAP 02224 shows a large variation of Pb/Pb age, from 3109±29 to 3547±21 Ma (2σ), much older than the whole-rock age of the same meteorite (~3.02±0.03 Ga). The other baddeleyite grain in LAP 02224 has an age of 3005±17 Ma (2σ). The result indicates that the minimum crystallization age of LAP 02224 is ~3.55 Ga and the younger ages could reflect late thermal disturbance on U-Pb system.  相似文献   

GRV 051523： A new eucrite     

刘焘  林杨挺  胡森  冯璐 《极地研究(英文版)》2009,20(2):200-208

Grove Mountains (GRV) 051523 is a newly identified eucrite, consisting mainly of coarse-grained pyroxene (62.9 vol%) and plagioclase (34.2 vol%), with less abundant opaque minerals (2.7 vol%), minor silica and tiny FeO-rich olivine (Fa75). Coarse-grained pyroxenes show exsolution of augite lamellae in pigeonite or vice versa. Width of most exsolution lamellae in pyroxenes is 1-3 μm. Opaque minerals are mainly chromite, ilmenite and sulfides. The meteorite was heavily shocked, as indicated by breccias and melt veins. Coarse-grained pyroxenes commonly contain abundant tiny or needle-like chromite inclusions with orientation, probably due to heavy shock events. Pyroxenes in various petrographic occurrences exhibit highly homogeneous compositions, indicating that GRV 051523 experienced intense thermal metamorphism in the parent asteroid 4 Vesta. GRV 051523 is classified as Type 5-6. This new eucrite will have additional constraints on chemical composition, magmatic differentiation, multi-stage shock and thermal history of Vesta.  相似文献   

Geochemistry of the Martian Meteorite GRV 99027     

王鹤年  谢志东  梁英 《极地研究(英文版)》2009,20(2):110-134

GRV 90027 is a Martian lherzolitic shergottites (L-S) containing poikilitic, non-poikilitic, and melted pocket components. GRV 99027 is mainly composed of olive (55 vol%) and pyroxene (37.5 vol%), with minor maskelynite (6 vol%) and chromite (1.5 vol%), and trace whitelockite and troilite, ect. In this paper, the mineralogy and petrology of GRV 99027 are reported; in addition, the geochemical characteristics of the REEs and H isotopes in the GRV 99027 are also further investigated. The ΣREE in GRV 99027 is relatively low; HREEs are enriched in olivine and pyroxene grains; LREEs are enriched in plagioclase with a high positive Eu anomaly. High ΣREE value is found in rare mineral whitlockite (less than 0.2 vol%), LREE≈HREE, and whitlockite has a negative Eu anomaly. The REE distribution patterns of the whole -rock of GRV 99027 is similar to but different from that of other L-S Martian meteorites, indicating that they came from different location of Mars. GRV 99027 has a high δD value. Different water-bearing minerals give different contribution for δD value. The δD of phosphates generally does not correlate with water content, and δD has a weak negative correlation with water content. GRV 99027 can be classified as an L-S Martian meteorite based on mineralogical assemblage patterns, REE distribution patterns, and hydrogen isotope. The isotope data of Sr, Nd, Pb, Os and REE from other L-S Martian meteorites were collected to discuss the formation history of the GRV 99027. Similar to other L-S Martian meteorites, GRV 99027 originated from part of Mar's mantle; during one strong impact event about 4M years ago, the meteorites were ejected from deep mantle into space, and traveled for a different duration in space (indicated by different cosmic exposure time), and captured by the Earth later in different time, ultimately falling on the Antarctica as L-S Martian meteorites.  相似文献   

基于嫦娥一号CCD数据空间特征的特定目标识别     

陈伟涛  闫柏琨  张志 《国土资源遥感》2009,(4):40-44

基于嫦娥一号CCD数据的空间特征,开展月球表面陨石坑和线性构造目标识别的探索研究。利用图像边缘检测算法将影像分割成许多目标体;为了解决过度分割和错分问题,根据分割结果对分割后的目标体进行合并;为获取地质意义和语义信息更丰富的陨石坑和线性构造目标,将合并结果导入ArcGIS进行手动修改。最后,以影像数据的空间特征为基础,基于规则分类原理,根据研究需要设定不同的识别规则,进行陨石坑和线性构造的自动识别,取得了较好的效果。  相似文献   

Chemical compositions and cassfication of Grove Mountains （GRV） 98003 and other Chinese iron meteorites     

王道德  林杨挺 《极地研究(英文版)》2005,16(1):13-22

Concentrations of Cr, Co, Ni, Cu, Ga, Ge, As, Sb, W, Re, Ir, Pt and Au of two ungrouped iron meteorites, Grove Mountains （GRV） 98003 from Antarctica and Ujimqin, were measured using instrumental neutron activation analysis. According to the bulk chemistry, GRV 98003 is classified as a member of ⅠAB group, and Ujimqin as a unique one of ⅠAB iron meteorite complex. The elemental abundance pattern and correlation between elements （e. g. Ni-Au, Co-Au, As-Au, W- Au, Cu-Au, Sb-Au） of GRV 98003 are similar with those of NAW 468 （ⅠAB）, but significantly depleted in refractory siderophile elements （ Re, It） and moderate volatile elements （Ca, Ge） relative to the latter. In addition, we reclassify Nantan （ⅢCD） as a member of ⅠAB main group （MG） and Yongning （ⅠA） as a unique iron meteorite related with IAB iron meteorite complex.  相似文献   

富Co铁锰结壳铂族元素与铼-锇同位素组成及其意义   总被引：13，自引：0，他引：13  

姚德  张丽洁  初凤友  杜安道  刘心中  杨富贵 《海洋地质与第四纪地质》2002,22(3):53-58

用ICP－MS测定了太平洋富Co铁锰结壳铂族元素和铼－锇同位素组成。富Co铁锰结壳不仅异常富集铂族元素，而且铂族元素及其它亲铁元素的配发与陨石特征非常相似。铁锰结壳的铼－锇同位素组成明显有别于大陆地壳岩石，和K－T界线沉积物相似，接近陨石值。世界大洋范围内的富Co铁锰结壳均产于远离海底构造热液活动区，几乎不可能受到地幔源热液作用的直接影响。因此，富Co铁锰结壳中的铂族元素可能部分来源于地外物质。  相似文献